1-(4-Fluorophenyl)thiourea
نویسندگان
چکیده
In the title compound, C(7)H(7)FN(2)S, the aromatic ring plane and the thio-urea unit are twisted with a torsion angle C-C-N-C7 of 44.6 (2)°. In the crystal, N-H⋯S and N-H⋯F inter-molecular hydrogen bonds link the mol-ecules into infinite sheets that are stacked along the c axis.
منابع مشابه
1-(2-Fluorophenyl)-3-(3,4,5-trimethoxybenzoyl)thiourea
The two m-meth-oxy groups of the title compound, C(17)H(17)FN(2)O(4)S, are almost coplanar with the aromatic ring [CH(3)-O-C-C = 5.8 (1) and 5.9 (1)°], whereas the meth-oxy group in the para position is bent out of the ring plane [78.6 (1)°]. Mol-ecules are connected by inter-molecular N-H⋯S hydrogen bonds to form centrosymmetric dimers that are stacked along the a axis.
متن کامل1-(Adamantan-1-yl)-3-(4-fluorophenyl)thiourea
In the title mol-ecule, C(17)H(21)FN(2)S, the mean planes of the benzene ring and the thio-urea fragment form a dihedral angle of 61.93 (9)°. In the crystal, pairs of weak N-H⋯S inter-actions link the mol-ecules, forming inversion dimers.
متن کاملN-(4-Chlorobenzoyl)-N′-(3-fluorophenyl)thiourea
In the title compound, C(14)H(10)ClFN(2)OS, the mol-ecule adopts a trans-cis geometry of the thio-urea unit. The dihedral angles between the benzene rings is 34.47 (7)°. The crystal packing features inter-molecular N-H⋯S and C-H⋯O hydrogen bonds, forming a chain along the b axis. A short C-H⋯S intramolecular contact is also observed.
متن کامل(4-Fluorophenyl)thiourea–1,10-phenanthroline (1/1)
Refluxing a mixture of 1,10-phenanthroline, (4-fluoro-phen-yl)thio-urea and cadmium(II) chloride did not produce the expected mixed-ligand complex but formed a co-crystal of the two ligands, C12H8N2·C7H7FN2S. The asymmetric unit consists of two pairs of the co-crystal mol-ecules. In each (4-fluoro-phen-yl)thio-urea mol-ecule, the planes of the N2CS thio-urea units are almost perpendicular to th...
متن کاملN-(4-Chlorobutanoyl)-N′-(2-fluorophenyl)thiourea
In the title compound, C(11)H(12)ClFN(2)OS, the asymmetric unit consists of two indenpendent mol-ecules. Both mol-ecules maintain a trans-cis configuration of the positions of the butanoyl and fluoro-phenyl groups with respect to the thiono group across their C-N bonds and are stabilized by classical intra-molecular N-H⋯O hydrogen bonds. In the crystal, inter-molecular N-H⋯O, C-H⋯S and N-H⋯S hy...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010